Important Fuels and their Energy content

Important Fuels and their Energy content:

1. Coal –

Coal is a rock formed from ancient plants that have been decomposed and heated under pressure underground. This process is called metamorphism. Coal varies widely in its composition, as it is a complicated mixture of hydrocarbons and carbohydrates, with small amounts of nitrogen, sulphur, water and minerals. It must be mined from the ground, either from deep mines (which creates spoil heaps), or by open-cast surface mining (which devastates the landscape). There are enough reserves for 200–250 years at the present rate of consumption.

Coal burns in air with a yellow smoky flame, leaving ash behind. The energy content of coal depends upon its type. The heat of combustion of brown coal or lignite is about 25 kJ/g, but the heat of combustion of bituminous coal (used in industry) and anthracite (used in homes) is about 32 kJ/g. When coal burns, it produces water and carbon dioxide. It also produces harmful sulphur dioxide, carbon monoxide, oxides of nitrogen (known as NOx), hydrocarbons and soot.

Coal cannot be used in cars and aircraft, but it can be converted into gaseous or liquid fuel. This fuel can be used to power diesel engines, and German aircraft flew using it in the Second World War. The“liquefaction plants” needed to make it produce carcinogenic (cancer-causing) hydrocarbons.

2. Natural Gas –

Natural gas is nearly always found associated with oil (see the Oil sheet). It consists almost entirely of methane. For example, the Frigg gas field in the North Sea produces gas which is 95% methane and 4% ethane, with only traces of other hydrocarbons. It has no smell and does not contain carbon monoxide, so it is not poisonous. However, it can asphyxiate (suffocate), and so an artificial smell is added before it is distributed so that leaks can be detected.

Natural gas ignites easily, and will cause explosions if sufficiently large quantities escape. It is a relatively clean fuel, and produces only carbon dioxide and water when it burns completely. Its heat of combustion is –890.3 kJ/mol, equivalent to an energy content of 55.6 kJ/g. There are sufficient reserves of natural gas for only 20 years at the present rate of consumption. However, rotting rubbish in landfill sites generates it, and some companies are now pumping it out for sale. It also can be produced by deliberate production of “biogas”, which is about 50% methane. Biogas is produced from decaying organic matter in biogas digesters, and is particularly popular in India and China.

Natural gas is not very portable, and is usually delivered to the customer through underground pipes. It can be liquefied to form NGL (natural gas liquid). This is different from LPG (liquid petroleum gas), which is a liquefied by-product of oil refineries). NGL (and LPG) can be used to power vehicles, and some experimental aircraft.

3. Ethanol –

Ethanol is a member of a large class of compounds called alcohols. It is a colourless liquid (boiling point 78ºC) which will mix with water. It can be made by reacting ethene (a product of crude oil) and water at 300ºC and high pressure with phosphoric acid as a catalyst. It can also be produced from carbohydrates, such as sugar, by fermentation using yeast. This is the method of choice for producing alcoholic drinks.

Ethanol burns very easily with a pale yellow flame to form carbon dioxide and water. Its heat of combustion is –1367.3 kJ/mol, which is equivalent to an energy content of 29.6 kJ/g. Alcohol has been used as a fuel for a long time, for example in spirit lamps and as methylated spirits. It is relatively safe and easy to transport, as it is a liquid. Petrol can be blended with up to 20% ethanol for use in an ordinary car engine without adjustment. Recently, ethanol has been produced by fermentation in industrial quantities to power vehicles. Brazil, in its Proalcohol programme, produces 3,200 million litres of ethanol (“Gasohol”) per year from crops such as sugar cane, sorghum and cassava. Brazil has also designed and manufactured cars to run on pure ethanol. The fuel is more expensive than petrol, but effectively is a renewable energy source and does not have to be imported. However, it is doubtful that hungry people see this as a benefit.

4. Hydrogen –

Hydrogen is the most abundant element in the Universe, but on Earth free hydrogen is less than one part per million of the atmosphere. However, it is abundant on Earth in the form of water, which is an almost inexhaustible supply of the element.

Several million tonnes of hydrogen are manufactured in the world each year, including 500,000 tonnes per year in the U.K. It can be made by the electrolysis of brine (sodium chloride solution), but this process is expensive and inefficient. Other methods include passing steam over white-hot coke (the Bosch or Water Gas Process), and the oxidation of natural gas using a catalyst. It is also found as a by-product in oil refineries.

When hydrogen burns completely, the only product is water. The heat of combustion for hydrogen is –285.8 kJ/mol, which is equivalent to an energy content of 142.9 kJ/g. Hydrogen is very easy to ignite, and caused dreadful accidents (such as the famous “Hindenburg” disaster) when used to lift airships in the days before helium became plentiful. Hydrogen is stored in gas cylinders or liquid containers, allowing it to be used in some domestic or industrial situations where natural gas might be used. It would be difficult to use in cars or aircraft in this way, but large quantities can be absorbed by expensive metals such as palladium, and released later by warming.

5. Summary - Average energy content of coal, oil and natural gas:

Crude Oil - 47.9 kJ/g

Natural Gas - 55.6 kJ/g

Lignite Coal - 25 kJ/g

Bituminous and Anthracite coal - 32 kJ/g

Oil from coal:

Oil from coal:

As petroleum price is increasing due to various reasons, the alternative methods of producing oil gained much importance. The most widely known alternatives involve in extracting oil from sources such as Natural gas (methane), coal, oil shale and tar sands. Though some these sources exist in large quantities, it has become a challenge to extract oil economically and without excessively harming environment. Therefore, in this respect, extraction of oil from coal or from natural gas has been significant.

In fact, technology to extract oil from natural gas or from coal was available since the world war – II; but it was not so much significant until the exorbitant hike in international crude oil prices in last decade. During the World war – II, Germany produced some quantity of oil from coal and there after, South Africa (Sasol) was the major country to produce oil from coal, to meet its energy needs during its isolation under Apartheid. As crude oil prices increase, the cost of coal to oil conversion becomes comparatively cheaper. Now, many countries like China, whose coal production is quite substantial but have less reserve of crude oil, have started producing oil from coal. Recently, India has also started thinking of such conversion of their coal to synthetic oil. This conversion process produces low sulfur diesel fuel but also produces large amounts of greenhouse gases.

The Fischer-Tropsch process is well known for conversion of coal to oil. It is a catalyzed chemical reaction in which carbon monoxide (CO) and hydrogen (H2) are converted into liquid hydrocarbons of various forms. Typical catalysts used are based on iron and cobalt. The principal purpose of this process is to produce a synthetic petroleum substitute, typically from coal, natural gas or biomass.

There is another process called Karrick process for conversion of coal to synthetic oil. It is a low temperature carbonization (LTC) of coal, shale, lignite or any carbonaceous materials. These are heated at 360 degree Celsius to 749 degree Celsius, in the absence of air to distill out oil and gas. Recently, China has announced high volume commercial coal liquefaction production by this method.

Coal bed methane (CBM) drainage - Potential uses of coal mines methane:

Coal bed methane (CBM) drainage - Potential uses of coal mines methane:

One of the major decisions facing a mine owner, when considering the implementation of a CBM drainage program is the potential use for the gas. The gas is a clean energy resource. However, the location of the mine and the ability to convert the gas into a marketable product may severely test the mine planners’ perseverance in finding an economic way of using the gas and producing the accompanying reduction in greenhouse gases. Here we would try to outline some possibilities for the gas whether it is a high-Btu, medium-Btu, or low-Btu product.

(1) High-Btu Gas (> 950 Btu/scf) - High-Btu gas is generally defined as having enough heat content to be used in a natural gas pipeline. Several potential uses exist for high-Btu gas. If the drainage system provides primarily CH4 and little in the way of inert gas, the product may be gathered, compressed, and marketed to a pipeline company. This is one of the most desirable options if natural gas pipelines are located near the mine. Thus, marketing of coal mines methane to a pipeline company would be a very desirable goal.

In case, pipelines are not readily available or the pipeline companies are not ready to buy coal mines methane, several other options are available for high-Btu gas. The first of these would be to use the gas as a feedstock to produce ammonia, methanol, or acetic acid. Currently, these chemicals are produced from natural gas, but coal-bed methane would be equally useful if it is available in sufficient quantities and if the chemical plants were in a favorable location. Another potential method of using CBM would be to compress or liquefy it for use in buses, trucks, and automobiles. This implementation has been successfully used in many of the CIS countries like Ukraine, Czech Republic etc.

(2) Medium-Btu Gas (300 to 950 Btu/scf) - There are many possible uses for medium-Btu gas. If the gas is at the high end of the heat content scale, enrichment by blending with a higher-quality gas or ‘spiking’ of the gas to produce a gas of pipeline quality is possible. Enrichment is the removal of gases like nitrogen, oxygen, and carbon dioxide to improve the heat content of the gas. ‘Spiking’ is the process of combining another fuel gas (like propane) with the methane to increase the heat content. Spiking will normally be economic only if the supplement gas is available cheaply in the area. A major and growing use of medium-Btu gas is as a substitute for other fuels in space heating and other applications where natural gas, fuel oil, or coal is normally used. For example, CBM can be used for heating mine facilities, heating mine intake air, heating greenhouses and institutional facilities, as a heat source in a thermal dryer and as a heat source for treating brine water.

Another use for medium-Btu methane is in electric power production. Using methane in coal-fired utility and industrial boilers and as a supplement to natural gas in blast furnaces is common where methane is extracted from coal mines.

(3) Low-Btu Gas (<>

Summery of specific options for utilization of Coal-bed methane from mines: a. Power Generation - CBM can be ideal fuel for co-generation Power plants to bring in higher efficiency and is preferred fuel for new thermal power plant on count of lower capital investment and higher operational efficiency. b. Auto Fuel in form of Compressed Natural Gas (CNG) - CNG is already an established clean and environment friendly fuel. Depending upon the availability of CBM, this could be a good end use. Utilization of recovered CBM as fuel in form of CNG for mine dump truck is a good option. c. Feed stock for Fertilizer – Many of the fertilizer plants in the vicinity of coal mines where coal-bed methane is drained, have started utilizing fuel oil as feedstock for its cracker complex. d. Use of CBM at Steel Plants - Blast furnace operations use metallurgical coke to produce most of the energy required to melt the iron ore to iron. Since coke is becoming increasingly expensive, in the countries where CBM is available, the steel industry is seeking low-capital options that reduce coke consumption, increase productivity and reduce operating costs. e. Fuel for Industrial Use - It may provide an economical fuel for a number of industries like cement plant, refractory, steel rolling mills etc. f. CBM use in Methanol production - Methanol is a key component of many products. Methanol and gasoline blends are common in many countries for use in road vehicles. Formaldehyde resins and acetic acid are the major raw material in the chemical industry, manufactured from methanol. g. Other uses - Besides above, option for linkages of coal-bed methane produced by coal mines, through cross country pipe lines may be considered.